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African Killer Lakes (CO2 / Methane Erupters: Kivu, Nyos & Monoun)

A

Anonymous

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Natural event or chemical weapons testing?

"Aug 15, 1984. The village of Njindom, Cameroon. About 11:30pm, the villagers heard a loud explosion coming from Lake Monoun. Early the next morning, people in a van driving past the lake discovered the body of a motorcyclist. The air smelled like battery fluid. One of the van's occupants collapsed. The others ran for their lives towards Njindom. By 10:30 am authorities had found 37 bodies along a 200 meter stretch of road by the lake. Blood was oozing from their noses and mouths; the bodies were rigid; first-degree chemical burns were present. Also, animals and plants along the shore had been killed. Lake Monoun is a volcanic crater lake, though tests ruled out geolical activity."
Science News, 128:356, 1985.
 
Interesting location. The last poison gas eruption that I know of was in Cameroon. If I remember this correctly, a large "bubble" of CO2 erupted from a lake, and killed (by suffication) a very large number of people. There is currently a lot of discussion going on about how to "defuse" a lake where there is a build-up of toxic gas at the lake bed. The case that you describe sounds very similar to this, though the gas appears to be somewhat different. The lack of a geological event is consistent with this hypothesis, as more or less anything could trigger the release. (The gas slowly builds up at the lake bed until it finally "bubbles-up".)
 
You're right, I found a further report which says a few days later, the lake had turned a weird colour, as if it had been stirred up by some activity on the bed. Interesting though.
 
The battery smell suggests that hydrogen sulphide was the culprit.

H2S is sometimes released by volcanoes and is responsible for the 'poison wells' feared by oil drillers.
 
The later report suggests that nitric acid may have been present, and then goes on to mention tales of "evil winds" (that's me after a curry...) that seem to affect some remote areas of africa.
It seems that co2, methane or other gasses may accumulate in some areas such as valleys, and animals or people travelling through may succumb to the fumes. Interesting stuff! This may also explain tales of elephant graveyards too.
 
naitaka said:
H2S is sometimes released by volcanoes and is responsible for the 'poison wells' feared by oil drillers.
I have worked as a well-logger on drilling rigs (Mr. Jack of all trades, me!), but I do not recall this feature. Since oil is mostly found in deep sedimentary strata, drilling is unlikely to take place near active volcanic features, I'd have thought.

Any more info?
 
Well, the North Sea is pretty shallow, although it all depends on what we classify as what deep actually means, regardless of that though, drilling holes near a chamber isn't a good move :)

It makes me wonder how oil would be recoverable near any volcanic activity, due to the relatively recent age, the high amounts of heat present, and the deformation of any sediment when the magma plume rises :confused:

It makes me wonder if significant amounts of H2S are released from certain types of oil, as for some reason when I think of African oil deposits, all I can remember is sulphur and/or shale :eek:
 
Several things still bother me about this one still:

The report says the lake clouded over several days later, not an indication of lake bed disturbance *at the time of the event*.

There is no mention of harm to aquatic life, no dead or burned fish or disturbed vegetation.

The origin of the hypothetical "nitric acid".

The jury is still out....
 
Tubal Cain said:
Several things still bother me about this one still:

The report says the lake clouded over several days later, not an indication of lake bed disturbance *at the time of the event*.

There is no mention of harm to aquatic life, no dead or burned fish or disturbed vegetation.

The origin of the hypothetical "nitric acid".

The jury is still out....

The nitric acid bit could be a a by-product of having oxides of nitrogen in the gas that bubbled up. (Though I can't say for certain why they would be present...)

:)
 
There was an article in New Scientist - not sure of the date, but you can look the article up at http://www.newscientist.com - relating to the Cameroon phenomenon. Apparently, they are trying to drain the lake of the natural CO2 it contains before another explosion happens.
 
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Interesting location. The last poison gas eruption that I know of was in Cameroon. If I remember this correctly, a large "bubble" of CO2 erupted from a lake, and killed (by suffication) a very large number of people. There is currently a lot of discussion going on about how to "defuse" a lake where there is a build-up of toxic gas at the lake bed. The case that you describe sounds very similar to this, though the gas appears to be somewhat different. The lack of a geological event is consistent with this hypothesis, as more or less anything could trigger the release. (The gas slowly builds up at the lake bed until it finally "bubbles-up".)

There was a show on Horizon (uk) about it..... details and a transcript are here
 
Remember this...

Killer lakes in Cameroon may strike again

Efforts to prevent the release of deadly clouds of toxic gas from two African lakes appear to be failing.

According to George Kling at the University of Michigan, US, unless urgent action is taken there is a real risk of a repeat of the tragic events of the 1980s when the lakes Nyos and Monoun in Cameroon suddenly released huge clouds of carbon dioxide into the atmosphere, killing 1800 people.

The dissolved gas is created by volcanic activity beneath the lakes and can gradually build up to dangerous levels before suddenly being released. To try to prevent this from happening again, a venting pipe was placed in Lake Nyos in 2001 and another in Lake Monoun in 2003 to allow the gas to be released at safe concentrations.

But having analysed 12 years’ worth of data on the lakes, Kling and colleagues have found that, although gradually reducing the CO2 content of the lakes without running the risk of triggering another massive release, the pipes are not working fast enough.

Extra pipes
Because of the rate the lakes are refilling with gas and because the reducing pressure at each pipe inlet will gradually reduce the removal rate, the current pipes are only predicted to remove 10 per cent of the total gas in the next year. Adding pipes might help avert a crisis, say the researchers.

“This slow removal extends the present risk to local populations,” says Kling. “Our model indicates that 75-99% of the gas remaining would be removed by 2010 with two pipes in Monoun and five pipes in Nyos, substantially reducing the risks.”
http://www.newscientist.com/article.ns?id=dn8053
 
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Poisonous gas from African lake poses threat to millions
Trapped methane and carbon dioxide could be set loose by a quake or landslide, say scientists
Robin McKie, science editor The Observer, Sunday 26 July 2009

More than two million people living on the banks of Lake Kivu in central Africa are at risk of being asphyxiated by gases building up beneath its surface, scientists have warned.

It is estimated that the lake, which straddles the borders of the Democratic Republic of Congo and Rwanda, now contains 300 cubic kilometres of carbon dioxide and 60 cubic kilometres of methane that have bubbled into the Kivu from volcanic vents. The gases are trapped in layers 80 metres below the lake's surface by the intense water pressures there. However, researchers have warned that geological or volcanic events could disturb these waters and release the gases.

The impact would be devastating, as was demonstrated on 21 August 1986 at Lake Nyos in Cameroon, in West Africa. Its waters were saturated with carbon dioxide and a major disturbance - most probably a landslide - caused a huge cloud of carbon dioxide to bubble up from its depths and to pour down the valleys that lead from the crater lake.

Carbon dioxide is denser than air, so that the 50mph cloud hugged the ground and smothered everything in its path. Some 1,700 people were suffocated.

"The lake was essentially like a bottle of beer that had been shaken up," said Professor George Kling, of the department of ecology and evolutionary biology at Michigan University. "When you opened it, carbon dioxide bubbled up, and the beer frothed over. A glassful is OK. A lakeful is deadly."

Kling has since turned his attention to Lake Kivu, which is more than 3,000 times the size of Nyos and contains more than 350 times as much gas. More worrying is the fact that the shores of Kivu are much more heavily populated. About two million people live there, including the 250,000 citizens of the city of Goma.

Mount Nyiragongo, near Goma, erupted in 2002 and lava streamed from it into Lake Kivu for several days. On this occasion there was no disturbance of the lake's deep layers of gas and no deadly outpouring of carbon dioxide or methane. However, Kling has warned - in the journal Nature this month - that in the event of another eruption the region may not be so lucky again.

Indeed, the impact would dwarf the disaster that struck Nyos. "Kivu is basically the nasty big brother of Nyos," Kling told Nature.

The source of Kivu's problems stems from carbon dioxide that has bubbled up through the lake bed from molten rocks below. The region - in Africa's Great Rift Valley - is a centre of volcanic activity. In addition, some of this carbon dioxide has been converted by bacteria in the lake into methane. Hence the accumulation of both gases.

According to studies by researchers at the Swiss Federal Institute of Aquatic Science and Technology, there was a 10% rise in carbon dioxide concentration, and a 15-20% increase in methane concentration in Kivu between 1974 and 2004. At the same time, plankton fossils on the lake's bed have revealed several massive bouts of biological extinctions in Kivu over thousands of years. However, it is impossible to say if a new one is imminent, researchers told Nature.

At the same time, engineers are trying to tap Kivu's rich supplies of methane - by lowering pipes from floating platforms down to its holding layers and siphoning off the gas. This could then be burnt and used as a source of industrial and domestic energy.

Several projects have been established, though only one is currently generating electricity - albeit sporadically - for the Rwandan grid. Another platform sank last year shortly before it was scheduled to begin production.

Tapping Kivu's methane could, theoretically, reduce the risk of a deadly eruption, say engineers. However, scientists have also warned that tampering with the lake's gases also carries a risk of triggering a disaster.

http://www.guardian.co.uk/world/2009/ju ... vu-co2-gas
 
Battle to degas deadly lakes continues
http://www.nature.com/news/2010/100823/ ... 1033a.html

Funding shortage is biggest hurdle for those striving to disarm three rare but lethal geological hazards.

Nicola Jones
A plume of gassy water spewing from Lake Nyos.M. HALBWACHS

After nearly a decade, a scheme to suck a deadly build-up of carbon dioxide out of Lake Nyos is nearing its final stages, say project scientists. But two other African lakes may still harbour serious dangers — now or in the future.

Located in a volcanic crater in a remote area of Cameroon, Lake Nyos captured the world's attention in 1986, when an explosive release of CO2 from the lake's depths asphyxiated 1,700 people in the surrounding villages. Gas had been seeping into the lake over decades or possibly centuries from the magma deep below. The dense, gas-filled water had been trapped in a layer near the lake bottom until an event, perhaps a landslide or heavy rainfall, stirred the lake and triggered release of the gas — a limnic eruption. The mass suffocation drew attention to a rare but lethal natural hazard and prompted scientists to consider ways of reducing the risk of it reoccurring.

In 2001, a team led by the physicist and engineer Michel Halbwachs, then of the University of Savoie in Chambéry, France, inserted a long pipe into the middle of Lake Nyos and started to siphon up the gassy water from the lake depths. The siphoned water releases its CO2 as it spews champagne-like from the top of the pipe, then falls harmlessly back onto the lake. In this way, the size of the gas-charged layer below and the risk it poses steadily decrease.

Despite setbacks, the basic strategy is working, says Halbwachs, who is now head of the gas-extraction company Data Environnement, based in Chambéry. But one pipe makes for a slow extraction, leaving villagers at risk. The plan called for more pipes to be installed, but funds were not forthcoming. After campaigning for more than a decade, Halbwachs says that he has secured donations of €1.4 million (US$1.8 million) from the United Nations Development Programme for two more pipes, which he hopes to deploy in Lake Nyos between November 2010 and February 2011. "The long delay is normal with international donors," says Halbwachs, who estimates that new pipes should make the region around Lake Nyos safe from a limnic eruption within 5 years.

Click for a larger version.

"This is a big success story," says George Kling, a biogeochemist at the University of Michigan in Ann Arbor who has been studying the lake for decades. But he worries that the schedule may slip again. "I've heard lots of dates before about when the pipes are actually going in," he says. "For the sake of the people there, I hope something gets done sooner rather than later."

Kling adds that other lakes still pose a threat. "We haven't solved all the problems. We need to remind government officials that scientists are still worried."

At nearby Lake Monoun, where a similar limnic eruption killed 37 people in 1984, a pipe that Halbwachs has been operating since 2003, along with two more added in 2006, has succeeded in degassing the deep waters. Halbwachs has declared the lake safe. But Kling suggests that new problems may lie ahead. Now that years of siphoning have effectively eliminated the separation of the lake's waters into layers, new gas entering from the lake bed could mix into a larger volume of water than before. According to Kling, it is harder to deal with more gas at a lower concentration because the gas pressure is insufficient to drive water up the pipes.

Takeshi Ohba, a geochemist at Tokai University in Hiratsuka, Japan, is in the process of securing more than $4 million, half from the Japan Science and Technology Agency and half from the Japan International Cooperation Agency, to help create a more permanent solution for Lake Monoun. His team plans to visit the area in February 2011 to help train local scientists and develop a pump that can extract the gassy bottom waters.

The problems are different at Lake Kivu, which borders Rwanda and the Democratic Republic of the Congo. Lake Kivu's deep waters hold CO2 and methane. Several commercial projects are under way to extract the methane and turn it into energy (see Nature 460, 321–323; 2009). So far, one 4?megawatt power plant is up and running. A 3.6?megawatt plant, which Halbwachs is heading up, has been rebuilt after the first collection platform sank in 2008. This plant was trialled successfully in June this year but is not yet in operation. Both are small demonstration projects compared with what may come: several hundred-megawatt-scale plants are being planned. ...

Most of Lake Kivu is relatively stable, with the gas-rich waters sitting below 330 metres. But local regulations are urgently needed, says Kling, to ensure that the degassed water from the planned full-scale power plants is returned to the lake at places where it won't stir up the deep layers, increasing the risk of eruption. Care must also be taken not to threaten the resident fish — an important local food source — by disturbing nutrient and oxygen levels.

A far greater threat lurks in the Gulf of Kabuno, which is connected to Lake Kivu by a narrow strait and holds a dangerous amount of gas just 12 metres below its surface. The World Bank has pledged $3 million to degas the gulf, but Halbwachs says his company would need perhaps $2 million more before work could start. "It contains ten times more carbon dioxide than Nyos and is located in a very populated area," says Halbwachs.
http://www.nature.com/news/2010/100823/ ... 1033a.html
 
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Rwanda's deadly methane lake becomes source of future power


Beneath the calm waters of Lake Kivu lie vast but deadly reserves of methane and carbon dioxide, which Rwanda is tapping both to save lives and provide a lucrative power source.

Plans are in place to pump out enough gas for power that would nearly double Rwanda's current electricity capacity, as well as reducing the chance of what experts warn could be a potentially "catastrophic" natural disaster.
The glittering waters of the inland sea, which straddles the border of Rwanda and the Democratic Republic of Congo, contain a dangerous and potent mix of the dissolved gases that if disturbed would create a rare "limnic eruption" or "lake overturn", expert Matthew Yalire said.

Levels of carbon dioxide (Co2) and methane are large and dangerous enough to risk a sudden release that could cause a disastrous explosion, after which waves of Co2 would suffocate people and livestock around, explained Yalire, a researcher at the Goma Volcano Observatory, on the lake's DR Congo shore.

"Right now the lake is stable, but for how long?" asked Yalire, who believes that extracting potentially explosive methane is one way to help "stabilise" the lake. ...

Kivu is not unique: two other lakes in Cameroon—Monoun and Nyos—have similar high concentrations of the gases. In 1984, a limnic eruption killed 37 people around Lake Monoun, then in 1986 a similar disaster at Lake Nyos claimed more than 1,700 lives. These tragedies have been seen as dire warnings for people near Lake Kivu. ...

Stretching over 2,370 kilometres squared (915 miles squared) and plunging to some 485 metres (1,590 feet) deep, the lake holds some 60 billion cubic metres (2,118 billion cubic feet) of dissolved methane gas, and some 300 billion cubic metres (10,594 billion cubic feet) of carbon dioxide.

With some two million people living close to the lake shore in both Rwanda and DR Congo, any eruption could be disastrous ...
http://phys.org/news/2014-05-rwanda-dea ... ce.html#ms
 
This new Smithsonian Magazine article provides an update on Lake Kivu, its dangers, and the ongoing efforts to exploit the lake's methane to fuel electricity generation.
The Explosive Hazard Hiding in an African Lake

Rwanda’s Lake Kivu has dense depths packed with methane and carbon dioxide gas

... Straddling the border between Rwanda and the Democratic Republic of the Congo, Kivu is one of a string of lakes lining the East African Rift Valley where the African continent is being slowly pulled apart by tectonic forces. The resulting stresses thin the Earth’s crust and trigger volcanic activity, creating hot springs below Kivu that feed hot water, carbon dioxide and methane into the lake’s bottom layers. Microorganisms use some of the carbon dioxide, as well as organic matter sinking from above, to create energy, producing additional methane as a byproduct. Kivu’s great depth — more than 1,500 feet at its deepest point — creates so much pressure that these gases remain dissolved. ...

If Kivu were to experience a limnic eruption, says limnologist Sally MacIntyre of the University of California, Santa Barbara, “it would be completely catastrophic.”

This isn’t just a theoretical concern. Scientists have found what may be evidence of at least one previous limnic eruption at Kivu that likely occurred between 3,500 and 5,000 years ago, and possibly several more recent ones. Sediment cores taken from the bottom of the lake have revealed features known as brown layers that are unlike the surrounding sediments. These sediment bands are “very unusual, organic-rich layers,” Katsev says, that may be the result of eruptions. ...

In 2008, Rwanda launched a pilot program taking methane from the lake to burn as a natural gas and last year signed a contract to export bottled methane. A much larger program, called KivuWatt, came online in 2015.

The projects pump water from the deep layers of the lake, and as the pressure is reduced on that water, the gases are released. The methane is extracted to be used as fuel, and the carbon dioxide is pumped back down to the bottom of the lake. “They take this gas, ship it via pipeline onshore and burn it the way you would burn fossil fuels to generate electricity,” Katsev says.

This harvesting might help to reduce the risk from accumulated gas in the lake, though it won’t eliminate it. Still, for a lake with that much danger lurking below, anything helps. And for the region around the lake, it could be an important source of energy. Once KivuWatt is fully online, the 100 megawatts of power produced by that project alone will make a significant difference for Rwanda, a developing country that is aiming for universal access to electricity.

FULL STORY: https://www.smithsonianmag.com/science-nature/explosive-hazard-hiding-african-lake-180976024/
 
The DR Congo is in fear of deadly gases being released from a lake near the city of Goma.

"A sinister threat is lurking beneath a lake near the city of Goma in the Democratic Republic of Congo.

Scientists say underground magma has been flowing toward Lake Kivu since the deadly eruption of the nearby Mount Nyiragongo volcano on Saturday.

An eruption from under the lake could trigger the release of a lethal, suffocating cloud of gas, experts fear.

Known as a limnic eruption, this event poses a rare but potentially catastrophic risk to Goma's residents."

https://www.bbc.com/news/world-africa-57280509
 
This new ScienceAlert article provides an update on the killer lakes and the gas extraction / energy generation project on Lake Kivu.
'Killer Lake' in Africa Looks Like Paradise, But It's Hiding a Deadly Secret

The engineers aboard the floating power station on Lake Kivu could only watch nervously as the volcano in the distance erupted violently, sending tremors rumbling through the water beneath them.

It was not the lava shooting from Mount Nyiragongo last May that spooked them, but the enormous concentrations of potentially explosive gases within Kivu, one of Africa's great Rift lakes ...

Flanked by rolling green hills tumbling into glassy waters, Kivu is not quite the picture of tranquility it seems, according to Francois Darchambeau from KivuWatt, a company that extracts gas from the lake's waters for electricity.

Thousands of years of volcanic activity has caused a massive accumulation of methane and carbon dioxide to dissolve in the depths of Kivu – enough to prove monumentally destructive in the rare event they were released.

If triggered, a so-called limnic eruption would cause "a huge explosion of gas from deep waters to the surface" resulting in large waves and a poisonous gas cloud that would put the lives of millions at risk, said Darchambeau, environmental manager at KivuWatt.

"This is what we call a killer lake," the limnologist, or an expert in freshwater systems, told AFP.

Only three such lakes exist in the world: Kivu, and Lakes Nyos and Monoun in northwest Cameroon. ...
FULL STORY: https://www.sciencealert.com/killer...paradise-but-it-s-hiding-a-vast-deadly-secret
 
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